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Sample and instrument details are given with the spectrum Set 1 Sample: Conditions: Spectrometer: 1: 1D 1H Sample: 100mM in D2O, ref: DSS Conditions: temperature: 298K, pH: 7.4 Spectrometer: Bruker DMX - 600MHz 2: 2D [1H,1H]-TOCSY Sample: 100mM in D2O, ref: DSS Conditions: temperature: 298K, pH: 7.4 Spectrometer: Bruker DMX - 600MHz 3: 1D DEPT90 Sample: 100mM in D2O, ref: DSS Conditions: temperature: 298K, pH: 7.4 Spectrometer: Bruker DMX - 600MHz 4: 1D DEPT135 Sample: 100mM in D2O, ref: DSS Conditions: temperature: 298K, pH: 7.4 Spectrometer: Bruker DMX - 600MHz 5: 2D [1H,13C]-HSQC Sample: 100mM in D2O, ref: DSS Conditions: temperature: 298K, pH: 7.4 Spectrometer: Bruker DMX - 600MHz 6: 2D [1H,13C]-HMBC Sample: 100mM in D2O, ref: DSS Conditions: temperature: 298K, pH: 7.4 Spectrometer: Bruker DMX - 600MHz 7: 2D [1H,1H]-COSY Sample: 100mM in D2O, ref: DSS Conditions: temperature: 298K, pH: 7.4 Spectrometer: Bruker DMX - 600MHz 8: 2D [1H,13C]-HMQC Sample: 100mM in D2O, ref: DSS Conditions: temperature: 298K, pH: 7.4 Spectrometer: Bruker DMX - 600MHz

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In addition, MT2 receptors play a crucial role in the regulation of circadian rhythms, which include the circadian regulation of the blood pressure and heart rate